Classification of Alcohols and Phenols
− Classification of Alcohols
On the basis of type of chain
Aliphatic alcohols
When the hydroxyl group (-OH group) of an alcohol is attached to an aliphatic carbon chain (open chain), the alcohol is called an aliphatic alcohol.
Methanol
Butane-2,3-diol
Aromatic alcohols
When the hydroxyl group is attached to the carbon chain which is attached to an aromatic ring, the alcohol is known as aromatic alcohol.
Phenylmethanol
2-Phenylethanol
−Classification of Alcohols
On the basis of number of hydroxyl groups present
Monohydric, dihydric, trihydric and polyhydric alcohols contain 1, 2, 3 and many alcohols respectively.
Dihydric alcohol
Trihydric alcohol
Monohydric alcohol
Polyhydric alcohol
−Classification of Alocohols
As primary, secondary and tertiary alcohols
If the hydroxyl group is attached to a primary carbon, it is called primary alcohol. Similarly, secondary and tertiary alcohols are attached to secondary and tertiary carbons respectively.
Primary alcohol (1°)
Secondary alcohol (2°)
Tertiary alcohol (3°)
Classification of Phenols
Phenols are classified as monohydric, dihydric, trihydric, polyhydric etc.
Phenol
Benzene-1,2-diol
Benzene-1,3,5-triol
Question
Question : Classify the following as primary, secondary and tertiary alcohols
- (CH3)3CCH2OH
- CH2=CHCH2OH
- C6H5CH(OH)CH3
- (CH3)3COH
Answer : The answer is written in the following table :
Compound | Classification |
---|---|
(CH3)3CCH2OH | Primary alcohol |
CH2=CHCH2OH | Primary alcohol |
C6H5CH(OH)CH3 | Secondary alcohol |
(CH3)3COH | Tertiary alcohol |